Barbituric acid, ReagentPlus - 100G

Description

ReagentPlus®, 99%

Synonym: 2,4,6-Trihydroxypyrimidine, Malonylurea

CAS Number 67-52-7

Empirical Formula (Hill Notation) C4H4N2O3

Molecular Weight 128.09

General description

Barbituric acid is a useful acid for organic and drug syntheses. Its dihydrate form can be synthesized from barbituric acid via crystallization from aqueous solution. Crystal structure of barbituric acid (in tautomeric form) has been investigated by a three dimensional fourier transform method. Its enol crystal form has been reported to be thermodynamically stable.

Application

Barbituric acid (BA) may be used in the preparation of the corresponding hemiaminals, via chemoselective reduction in the presence of SmI2/H2O reagent. It may be used in the preparation of BA- modified conjugated carbon nitride nanosheets.

It may be used to synthesize:

• 5-ylidenebarbituric acid derivatives via Knoevenagel condensation with aromatic and α,β-conjugated aromatic aldehydes

• 5-diaminomethylenebarbiturates by reacting with substituted carbodiimides

Packaging

25, 100, 500 g in poly bottle

Safety Information

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

RIDADR NONH for all modes of transport

WGK Germany 1

RTECS CP8000000

Flash Point(F) 302 °F

Flash Point(C) 150 °C