1,5,7-Triazabicyclo[4.4.0]dec-5-ene 345571-5G

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Catalog/Part Number: 345571-5G
Brand: MERCK
Supplier: MERCK
Supplier Location: GERMANY
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Catalog/Part Number:: 345571-5G

₦76,560.00

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Description

General description

1,5,7-Triazabicyclo[4.4.0]dec-5-ene, a bicyclic guanidine base, has been found to be an excellent catalyst for Michael and Michael-type reactions.[1] It forms 1:1 complex with lasalocid acid and crystal structure of the complex has been studied by X-ray diffraction, FT-IR spectroscopy and 1H NMR.[4]

Application

1,5,7-Triazabicyclo[4.4.0]dec-5-ene may be used as organocatalyst for aminolysis of esters.[2] It may be used as catalyst for direct addition of P(O)-H bonds (dialkyl phosphites and diphenyl phosphonite) across various activated alkenes.[3] Polymer supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (PTBD) was used as a base and a reagent scavenger for the synthesis of aryl ethers from phenols and alkyl or aryl halides.[5]

Packaging

5 g in glass bottle

 

Catalog/Part Number: 345571-5G Category:

Technical Specifications

Related Categories



 Acids & Bases, Bases, Building Blocks, C6 to C8, Chemical Synthesis,
Heterocyclic Building Blocks, Organic Bases, Pyrimidines, Synthetic Reagents
Less...
assay   98%
mp   125-130 °C (lit.)
solubility   acetonitrile: soluble
  ethanol: soluble
  organic solvents: soluble
  water: soluble
SMILES string   C1CNC2=NCCCN2C1
InChI   1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key   FVKFHMNJTHKMRX-UHFFFAOYSA-N

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