1,4-Diazabicyclo[2.2.2]octane D27802-25G

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Catalog/Part Number: D27802-25G
Brand: MERCK
Supplier: MERCK
Supplier Location: GERMANY
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Catalog/Part Number:: D27802-25G

₦45,240.00

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Description

General description

1,4-Diazabicyclo[2.2.2]octane (DABCO, triethylenediamine), a caged tertiary diamine, is commonly used as an organic base in chemical synthesis.[1] It can also be employed as a complexing ligand and as a catalyst.[2] Its gas-phase electronic absorption spectrum,[3] vibrational spectra,[2] multiphoton ionization (MPI) and two-photon fluorescence excitation (TPFE) spectra[4] have been recorded and analyzed. Protonmagnetic resonance (PMR) studies of DABCO in solid state were conducted in order to determine its linewidth, second moment and spin-lattice relaxation time.[5]

Application

1,4-Diazabicyclo[2.2.2]octane (DABCO) may be used in the synthesis of isoxazole derivatives via dehydration of primary nitro compounds in the presence of dipolarophiles.[1] DABCO may be used in the preparation of the following:[6]
• DABCO bis(perhydrate)
• DABCO monohydrate
• DABCO hexahydrate

Packaging

2 kg in poly bottle

25, 100, 500 g in poly bottle

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

 

Catalog/Part Number: D27802-25G Category:

Technical Specifications

Related Categories


 Acids & Bases, Bases, Chemical Synthesis, Organic Bases, Synthetic Reagents More...
grade   ReagentPlus®
vapor pressure   2.9 mmHg ( 50 °C)
assay   ≥99%
refractive index   n20/D 1.4634 (lit.)
mp   156-159 °C (lit.)
density   1.02 g/mL at 25 °C (lit.)
SMILES string   N12CCN(CC2)CC1
InChI   1S/C6H12N2/c1-2-8-5-3-7(1)4-6-8/h1-6H2
InChI key   IMNIMPAHZVJRPE-UHFFFAOYSA-N

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